Summary

Compounds that contain an asymmetric carbon atom form stereoisomers that differ in their effect on plane polarised light. This type of isomerism is called optical isomerism.

Specification

Optical isomerism is a form of stereoisomerism and occurs as a result of chirality in molecules, limited to molecules with a single chiral centre.

An asymmetric carbon atom is chiral and gives rise to optical isomers (enantiomers), which exist as non superimposable mirror images and differ in their effect on plane polarised light.

A mixture of equal amounts of enantiomers is called a racemic mixture (racemate).

Students should be able to:

• draw the structural formulas and displayed formulas of enantiomers

• understand how racemic mixtures (racemates) are formed and why they are optically inactive.

Notes